Can't Connect to eDonkey2000?
1. Is eDonkey2000 enabled?
2. Is the host cache empty?
Enabling eDonkey2000
In the menu Tools, choose eTomi settings and go to Networks > eDonkey2000.

Check "Connect to eDonkey2000 today" and "Auto-connect every session". Press "OK" and wait a couple of seconds to see if eTomi connects.
Checking the eDonkey2000 host cache
To check, hit F8 to open the 'Host Cache' window. Switch to the eDonkey2000 cache by choosing the eDonkey Cache tab in the bottom right corner.

There should be many entries looking similar to this:

Refreshing the eDonkey2000 Serverlist
In the menu Tools, choose eTomi settings and go to Networks > eDonkey2000.

Choose "Download...". A dialog box with an URL will appear. Unfortunately, the URL displayed here by default doesn't seem to work anymore. Try to replace it with http://www.edonkey2000.com/server.met and click "OK" to get a new up-to-date list of eDonkey2000 servers. (Note: If you wish to insert another URL, you can google for 'server met' to find URLs of other server.met files.)
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Wait a moment
Wait a couple seconds, and see if eTomi begins to connect. If eTomi doesn't connect after reading this, try rebooting eTomi , or your computer.
Detail is a plus, and it would be helpful to mention you read this guide.